Crystal Structure of 2-Se-(2-methyl-2-propenyl)-1-benzoic Acid

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Crystal structure of 2-Se-(2-methyl-2-propenyl)-1-benzoic acid.

C11H12O2Se is triclinic, P1. Unit-cell dimensions at 293 K are a = 5.8450(10), b = 8.1490(10), c = 11.4620(10)A, alpha = 97.050(10), beta = 90.140(10), gamma = 90.120(10) degrees, V = 541.81(12)A3, Dx = 1.564 g/cm3, and Z = 2. The R value is 0.047 for 1388 observed reflections. The dihedral angle between the phenyl ring and the isobutenyl group is 72.3(2) degrees. There is an intermolecular hyd...

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In the title compound, C15H15N3O6, the dihedral angle between the planes of the benzene and imidazole rings is 34.93 (10)°. An intra-molecular C-H⋯O hydrogen bond is observed. In the crystal, O-H⋯N hydrogen bonds link the mol-ecules into chains parallel to the c axis.

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Crystal structure of 2-selenobenzyl-1-benzoic acid.

C14H12O2Se is monoclinic, P2(1)/c. Unit-cell dimensions at 293 K are a = 8.1055(7), b = 5.8403(11), c = 26.0302(17)A, beta = 94.560(5) degrees, V = 1228.3(3)A3, Dx = 1.575 g/cm3, and Z = 4. The R value is 0.048 for 2144 observed reflections. The dihedral angle between the phenyl rings is 74.9(2)degrees. There is an intermolecular hydrogen bond between two symmetry related carboxyl groups with a...

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2-Methyl-4-(2-methyl­benzamido)­benzoic acid

In the crystal structure of the title compound, C(16)H(15)NO(3), inter-molecular N-H⋯O hydrogen bonds link the mol-ecules into chains parallel to the b axis and pairs of inter-molecular O-H⋯O hydrogen bonds between inversion-related carb-oxy-lic acid groups link the mol-ecules into dimers. The dihedral angle between the two benzene rings is 82.4 (2)°.

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Crystal structure of 4-[1-(2-hy­droxy­prop­yl)-4,5-diphenyl-1H-imidazol-2-yl]benzoic acid

In the title compound, C25H22N2O3, the central imidazole ring makes dihedral angles of 48.43 (10), 20.23 (10) and 75.38 (11)° with the benzene ring and the two phenyl rings, respectively. The phenyl ring adjacent to the N-bonded 2-hy-droxy-propyl group shows the greatest twist, presumably to minimize steric inter-actions. In the crystal, mol-ecules are linked by O-H⋯N, O-H⋯O and C-H⋯O hydrogen ...

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ژورنال

عنوان ژورنال: Analytical Sciences

سال: 2003

ISSN: 0910-6340,1348-2246

DOI: 10.2116/analsci.19.1227